Research on the hydrogen injection strategy of a direct injection natural gas/hydrogen rotary engine considering apex seal leakage

The purpose of the present paper is to investigate the hydrogen injection strategy on the combustion performance of a natural gas/hydrogen rotary engine. Considering that apex seal leakage (ASL) is an inevitable problem in the actual working process of a rotary engine, the action of ASL cannot be ignored for an in-depth study of its combustion performance. Therefore, in this paper, a 3D dynamic simulation model that put the effect of ASL into consideration was established. Furthermore, based on the established 3D model, the combustion process of a natural gas/hydrogen rotary engine under various hydrogen injection angle (HIA) and hydrogen injection timing (HIT) was investigated. The results indicated that the hydrogen jet flow first impacted on the rotor wall after entering the cylinder, and then diffused under the action of the vortexes in the cylinder. Therefore, the HIA and HIT could change the hydrogen distribution by changing the hydrogen impact location and the intensities of the vortexes in the cylinder. In addition, the ideal hydrogen distribution at the ignition timing which could improve the combustion efficiency was given. That is, under the premise of ensuring minimized hydrogen leakage, the hydrogen should mainly distribute in the middle and the front of the cylinder, and a high hydrogen concentration is maintained near the spark plug.     

Experimental and computational study on the separation performance of an electrostatic precipitator with curved transvers collecting plates

Aiming at the problems of low collection efficiency of fine particulate matter and large area occupied by existing electrostatic precipitators (ESP), a new type of horizontal electrode ESP is proposed. It has the advantages of accelerating turbulent coalescence, increasing the effective dust collecting area and increasing the particle driving speed. The performance of the new type of ESP is systematic studied through simulation and experiment at the same time, and the results matches well. By comparing the dust removal effect of the horizontal electrode ESP and the conventional ESP, it can be concluded that the horizontal electrode ESP has a better dust removal efficiency, and can still maintain a better dust removal effect under high air velocity. The dust removal efficiency of new ESP can reach above 98% under the experimental conditions.     

Water electrolysis using plate electrodes in an electrode-paralleled non-uniform magnetic field

Compared with other ways to produce hydrogen, water electrolysis is the best way to obtain ultra-pure hydrogen, but its low energy efficiency greatly limits its wide application. It was proved that external magnetic field can reduce energy consumption, thereby increase electrolysis efficiency. Most of the researchers are focused on the impact of uniform magnetic field but few on a non-uniform one. To address the industrial operation reality, in our work, water electrolysis was operated using alkaline solution and plate electrodes in a non-uniform Magnetic field. The results show that a rotational flow on the vertical plane was formed by Lorentz force within the entire cell range. Although the entrainment effect of rotating flow made the cell full of microbubbles, the cell voltage was still reduced. By measuring the voltage difference of cathode side and anode side, we think that the bubble layer in the vicinity of the electrode surface matters the most among the sources of electric resistance. And the velocity distribution near the electrode was measured by PIV, it reveals that MHD flow is the dominant effect on the flow field of the cell. The results show that non-uniform magnetic field has potential merit in industrial electrolysis process.     

Potassium ions stabilized hollow Mn-based prussian blue analogue nanocubes as cathode for high performance sodium ions battery

Mn-based Prussian blue analogue is regarded as one of the promising cathodes for sodium ions battery owing to its high theoretical capacity and low cost. However, the unstable structure during charging/discharging process and the poor cycle life hinder its commercial application. In this work, potassium ions stabilized hollow Mn-based Prussian blue analogue is synthesized through a simple sodium citrate assisted method using for cathode of sodium-ions batteries. Although unique hollow structure could suffer volume variation during charging/discharging process, the K⁺ is introduced to further stabilize its structure. The PBAs cathode exhibits a high reversible specific capacity of 128 mA h g^?1 at 50 mA and superior rate performance of 72 mA h g^?1 at a high current density of 3200 mA g^?1, which is attributed to its stable structure and enhanced sodium ions transport kinetics. Ex-situ XRD/Raman tests and electrochemical measurements further prove the synergistic effect of various alkali ions (K⁺/Na⁺) and unique hollow structure. They work together to improve the structural stability and promote sodium ions diffusion rate of Mn-based PBAs.     

Design and synthesis of side-chain optimized poly(2,6-dimethyl-1,4-phenylene oxide)-g-poly(styrene sulfonic acid) as proton exchange membrane for fuel cell applications: Balancing the water-resistance and the sulfonation degree

Side-chain optimized poly (2,6-dimethyl-1,4-phenylene oxide)-g-poly (styrene sulfonic acid) (PPO-g-PSSA) is designed with balanced water-resistance and sulfonation degree. The PPO-g-PSSA is synthesized by controlled atom-transfer radical polymerization (ATRP) from brominated poly (2,6-dimethyl-1,4-phenylene oxide) (PPO-xBr) and ethyl styrene-4-sulfonate and followed by hydrolysis. A series of PPO-g-PSSA are prepared possessing different bromination degree (x) of PPO-xBr and polymerization degree (m) of the side-chains and the water-resistances of the fabricated membranes are investigated. The results show that a PPO-g-PSSA at relatively low x (x < 0.2) and high m (m > 4) exhibits good balance between the water-resistance and the sulfonation degree. Namely, it displays suitable proton conductivity with compromised water-resistance. Moreover, a maximum ion exchange capacity (IEC) of 3.24 mmol g^?1 is reached without the sacrifice of water-resistance. In addition, PPO-g-0.08PSSA-13 and PPO-g-0.14PSSA-4 are chosen characterized by thermogravimetric analysis, proton conductivities and mechanical properties. At 90% RH, the optimized PPO-g-0.08PPSA-13 possesses a proton conductivity of 37.9 mS cm^?1 at 40 °C and 45.5 mS cm^?1 at 95 °C, respectively.     

Evaluating the profile of myofibrillar proteins and its relationship with tenderness among five styles of dry-cured hams

In order to investigate the relationship between profile of myofibrillar proteins and tenderness among 2 kinds of Chinese hams (Jinhua and Xuanwei) and 3 kinds of European hams (Iberian, Serrano and Parma), shear force, myofibril fragmentation index (MFI), SDS-PAGE, carbonyls content and Raman spectroscopy were investigated. The shear force and salt content of Chinese hams were significantly higher than that of European hams, while moisture content was lower than that of European hams (p < 0.05). MFI values and SDS-PAGE profile revealed that the degradation of myofibrillar proteins in Chinese hams was lower than in European hams. In addition, Chinese hams showed significantly higher carbonyls content and β-sheet content compared with European hams, indicated that proteins aggregation intensively inhibited the degradation of myofibrillar proteins in Chinese hams. These results indicated that the higher shear force in Chinese style hams could be attributed to the lower moisture content and limited proteolysis.     

基于决策树的羽流追踪机器人自主决策方法研究

针对无法获得可靠羽流流向信息不利于实现羽流追踪的问题，提出了一种基于决策树的羽流追踪移动机器人自主决策方法。该方法通过移动机器人两侧的浓度传感器采集到的浓度信息，利用追踪的行为规则建立决策树模型，获得行为决策信息，使机器人高效地追踪到羽流并精确地定位。由于浓度变化关系蕴含了羽流的流向及流速信息，从而取代了传统方法中流向及流速传感器。在扩散环境下，通过移动机器人羽流追踪实验，实现了良好的源定位效果。     

A CCD-ADI method for two-dimensional linear and nonlinear hyperbolic telegraph equations with variable coefficients

In this paper, a combined compact finite difference method (CCD) together with alternating direction implicit (ADI) scheme is developed for two-dimensional linear and nonlinear hyperbolic telegraph equations with variable coefficients. The proposed CCD-ADI method is second-order accurate in time variable and sixth-order accurate in space variable. For the linear hyperbolic equation, the CCD-ADI method is shown to be unconditionally stable by using the Von Neumann stability analysis. Numerical results for both linear and nonlinear hyperbolic equations are presented to illustrate the high accuracy of the proposed method.     

西藏甲玛超大型斑岩成矿系统找矿方向

甲玛矿床位于西藏冈底斯成矿带，其勘查和研究程度均较高，矿体由斑岩型矿体、矽卡岩型矿体、角岩型矿体及外围独立金矿体组成，具有多元矿体结构，其成矿元素为Cu、Mo、Pb、Zn、Au和Ag，呈现多金属成矿作用特征。矿区深部及外围的勘查找矿方向一直是地质学者们关注的热点。在斑岩成矿系统理论的指导下，近年来在甲玛矿区深部及外围取得了重大找矿突破。基于最新勘查成果，甲玛矿床共探获铜资源储量超过850×10⁴ t，钼资源量达91×10⁴ t，铅锌资源量超过150×10⁴ t，伴生金储量为220 t，伴生银储量超过1×10⁴ t，达到超大型矿床规模。为进一步指导区域及外围勘查找矿工作，以甲玛矿区最新勘查成果为基础，通过对矿区钻孔的详细编录，采用地表构造蚀变填图等方法，系统解剖了甲玛矿区不同矿段的矿体地质结构，并揭示了其矿床地质特征。结合甲玛矿区新发现的主矿段深部的厚大矽卡岩矿体和外围则古朗北矿段的巨厚斑岩型矿体，分析了矿区深部及外围找矿潜力，认为甲玛矿区深部仍存在厚大矽卡岩铜钼矿体和斑岩钼矿体，应进一步加强对外围则古朗北矿段新发现的斑岩矿体、矽卡岩矿体和角岩型矿体的勘查，建立新的资源储备。此外，归纳总结有效勘查找矿方法，以期为深入探究甲玛矿床成矿作用和创建综合勘查找矿模型提供参考依据，并通过系统梳理矿区已有勘查和研究资料，总结甲玛矿床的找矿标志，为区域类似矿床的地质勘查提供重要线索，也为青藏高原斑岩成矿系统的勘查和研究工作奠定坚实基础。     

How hydrogen-storage material affects the decomposition of nitramine explosive: CPMD investigations of LAB-doped CL20

As the most popular high-energy explosives, 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazatetracyclo [5.5.0.0.0] dodecane (Simplified as HNIW or CL20) attracts many attentions for improving its detonation appearance in the application. Here we introduce hydrogen-storage compounds into explosives to estimate the possible improved detonation performances by Car-Parrinello molecular dynamics (CPMD) simulation, where we construct lithium amidoborane (LAB) doped CL20 as the initial structure. Almost all the interactions between hydrogen and CL20 appear exothermic properties, which indicate LAB increases the enthalpies of detonation. The results suggest explosive mixed with hydrogen-storage material is possibly a new field of energetic compound.